Using nitrogen in tires comes from racing tech, where it does have benefits, primarily with racing tires. Racing tires are very sensitive to heat, and the heat that a tire develops across its surface is very sensitive to tire pressure. One psi is a lot of error in a racing application. Because nitrogen is dry, it gives the tire a smaller, and more predictable pressure change with changing temperature, which makes it easier to optimize the performance of the tire. The nitrogen is also always the same, wheras the moisture content of air changes from day to day, and throughout the day.
Nitrogen is generally considered to be overkill for street applications. Granted, the lower moisture will prevent, or at least inhibit, internal corrosion, etc, but who has ever had a tire rust, or rot, from the inside ? I haven't, and no one I know has.
If your tires were filled with nitrogen, you can still use air, but you will reduce the original benefits by introducing some moisture. Likewise, if you refill an air-filled tire with nitrogen, you will be decreasing the relative amount of moisture in the tire. Both changes are proportional to the relative amounts of nitrogen and air in the tire, and, of course, to the relative humidity of the air with which the tire was filled. Arizona and Florida will see different results.